Structure of a heterobimetallic cobalt/platinum complex with unusual cobalt geometry
نویسندگان
چکیده
منابع مشابه
Synthesis, Identification and Calculation of Complex Crystallographic Structure of Cobalt (II) with theLigand Heterocyclic Derived from Pyridine
A novel Pyridine-2,6-dicarboxylic acid mixed ligands complex of formula [Co(NO3)2].6H2O has been obtained by the reaction of Pyridine-2,6-dicarboxylic acid with cobalt nitrate and 1,10-phenanthroline on heating in water. The structures of [Co(pydc)(Phen)(H2O)](pydcH2).4H2O receptors, and their complexes were optimized using DFT method at the B3LYP/3-21G** level. The highest occupied molecular o...
متن کاملElectronic structure and electron transport characteristics of a cobalt complex.
The molecular and electronic structures and electron transport characteristics of a Co complex are investigated using first principles calculations. The Co complex belongs to the D(2d) point group, and its two ligands are perpendicular to each other. The central atom Co forms a distorted octahedron with six donor N atoms. In a low oxidation state, the bond length between Co and pyrrole nitrogen...
متن کاملSynthesis, Characterization and X-Ray Crystal Structure of a Cobalt(III) Complex with 2-Bis(pyridine-2-carboxamido)-4,5-dimethylbenzene Ligand
An octahedral cobalt(III) complex, trans-[(Me2bpb)Co(bzlan)2]ClO4 (1), with H2Me2bpb = N,N’-(4,5-dimethyl-1,2-phenylene)dipicolinamide and bzlan = benzylamine, has been synthesized and characterized by elemental analyses, IR, UV-Vis, and 1H NMR spectroscopy. The structure of this complex has been determined by X-ray crystallography. The Me2bpb2– is a di-anionic tetradentate ligand furnishing a ...
متن کاملOn Hyperbolic Geometry Structure of Complex Networks
Various real world phenomena can be modeled by a notion called complex network. Much effort has been devoted into understanding and manipulating this notion. Recent research hints that complex networks have an underlying hyperbolic geometry that gives them navigability, a highly desirable property observed in many complex networks. In this internship, a parameter called δ-hyperbolicity, which i...
متن کاملSynthesis of a new dithiocarbamate cobalt complex and its nanoparticles with the study of their biological properties
Nano dithiocarbamate (DTC) complex have been prepared by reaction between dithiocarbamate and metal salt under ultrasound irradiation. Reaction conditions such as the ligand DTC and phennantroline concentration, aging time and the ultrasonic device power show important roles in the size, morphology and growth process of the final products. The dithiocarbamate complex nanoparticles have been pre...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 1987
ISSN: 0108-7673
DOI: 10.1107/s0108767387080772